論文リスト (Publication List)
Sakai, G.; Tian, Y.; Zhu, B.; Omoda, T.; Yamamoto, K.; Tian, Y.; Zhu, B.;
Sakaki, S.; Murahashi, T.
To be submitted
Sasaki, K.; Takeuchi, S.; Ikeda, S.; Kondo, M.; Masaoka, S.; Yamamoto,
K.; Murahashi, T.
To be submitted
Inoue, I.; Aida, Y.; Omoda, T.; Yamamoto, K.; Murahashi, T.
To be submitted
Iwata, K.; Miyazawa, K.; Kurashima, K.; Zhu, B.; Tian, Y.; Ono, A.; Yamaura,
H.; Hatano, A.; Y. Takahira, Yamamoto, K.; Omoda, T.; Sakaki, S. Murahashi,
T.
To be submitted.
- "Palladium Cluster Complex [Pd13(μ4-C7H7)6]2+ (C7H7 = tropylium) with an fcc-Close-Packed Cuboctahedral Pd13 Core and Isomers: Theoretical Insight into Ligand-Control of the Pd13 Core Structure
Zhu, B.; Murahashi, T.; Sakaki, S.
Phys. Chem. Chem. Phys. 2023, 25, in press.
- "Isolation and Structures of Polyarene Palladium Nanoclusters"
Hatano, A.; Sugawa, T.; Mimura, R.; Kataoka, S.; Yamamoto, K.; Omoda, T.;
Zhu, B.; Tian, Y:, Sakaki, S.; Murahashi, T.
J. Am. Chem. Soc. 2023, 145, 15030-15035.
(Open Access)
FEATURED in the Cover.
HIGHLIGHTED in ChemistryViews
(Wiley-VCH & ChemPubSoc Europe)
- "Di- and Trinuclear Sandwich Complexes of a Cross-Conjugated Fulvene"
Kudo, E.; Oba, Y.; Yamamoto, K.; Murahashi, T.
Dalton Trans. 2023, 52, 1568-1573. 
- "Regio- and Diastereoselective Formal [2+2] Cycloaddition of Allenes
with Amino-Functionalized Alkenes by Rare-Earth-Catalyzed C(Sp2)-H Activation"
Xu, W.; Cong, X.; An, K.; Lou, S.; Li, Z.; Nishiura, M.; Murahashi, T.;
Hou, Z.
Angew. Chem. Int. Ed. 2022, 61, e202210624.
- "Multinuclear Coordination of Fused Benzene Ring Hydrocarbons"(Review)
Yamamoto, K.; Sugawa, T.; Murahashi, T.
Coord. Chem. Rev. 2022, 466, 214575
(Special Issue on "Current Coordination Chemistry in Japan")
- "Bridging Coordination of Acenaphthylene to a Pd3 Chain or a Pd4 Sheet Cluster"
Yamamoto, K.; Sugawa, T.; Kondo, M.; Masaoka, S.; Murahashi, T.
Dalton Trans. 2022, 51, 1901-1906.
- "Selective Dimerization of a Trinuclear Mixed-Metal Sandwich Complex:
Construction of an Axially Chiral Metal Skeleton"
Yamaura, H.; Yamamoto, K.; Murahashi, T.
Chem. Commun. 2021, 57, 9120-9123.
SELECTED in the themed collection "HOT articles" of Chem. Comm.
- "A Novel Method for Stereochemical Control of Carbon-Carbon Double
Bonds- E to Z Isomerization without Photo-irradiation" (in Japanese)
Murahashi, T.; Yamamoto, K.
Kagaku (Kyoto, Japan), 2021, 76, 12-16 (An account for public).
- "Heterometallic d8-d10 Coupling of Rh(I) and M(0) (M = Pd, Pt) in a Sandwich Framework of pπ-Conjugated
Ligands"
Inoue, I.; Yamamoto, K.; Sakaki, S.; Murahashi, T.
Chem. Eur. J. 2021, 27, 10558-10562.
FEATURED in the Cover.
- "Selective E to Z Isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism"
Kudo, E.; Sasaki, K.; Kawamata, S.; Yamamoto, K.; Murahashi, T.
Nature Commun. 2021, 12, 1473.
(Open Access)
HIGHLIGHTED by Tokyo Institute of Technology
FEATURED in Editor's Highlights
in Nature Communications
FEATURED in Kagaku, 2021, 76, 12 (in Japanese).
- "Thiophene- and Selenophene Binding at a Pd3 Cluster Site"
Yamamoto, K.; Sawada, J.; Murahashi, T.
Chem. Eur. J. 2020, 26, 8388-8392.
- "Exceeding Metal Capacity in Sandwich Complexes: Ligand-unsupported Docking of Extra Metal Moieties at Edges of a Metal Sheet Sandwich Complex"
Ishikawa, T.; Kawamura, A.; Sugawa, T.; Moridaira, R.;Yamamoto, K.; Murahashi, T.
Angew. Chem. Int. Ed. 2019, 58, 15318-15323
; Angew. Chem. 2019, 131, 15462-15467.
- "Photo-induced Translocation of a Pdn Moiety (n = 2, 7) on a Conjugated Polyene Ligand"
Yamashita, M.; Horiuchi, S.; Yamamoto, K.; Murahashi, T.
Dalton Trans. 2019, 48, 13149-13153.
- "Extended Open-Chain Polyenides as Versatile Delocalized Anion Ligands
for Metal Chain Clusters"
Yamashita, M.; Kawasumi, Y.; Tachibana, Y.; Horiuchi, S.; Yamamoto, K.;
Murahashi, T.
Chem. Eur. J. 2019, 25, 1212-1216
.
- "Three-Dimensional Sandwich Nanocubes Composed of 13-Atom Palladium
Core and Hexakis-Carbocycle Shell"
Teramoto, M.; Iwata, K.; Yamaura, H.; Kurashima, K.; Miyazawa, K.; Kurashige,
Y.; Yamamoto, K.; Murahashi, T.
J. Am. Chem. Soc. 2018, 140, 12682-12686
.
FEATURED in the Cover.
HIGHLIGHTED by Tokyo Institute of Technology
HIGHLIGHTED in ChemistryViews
(Wiley-VCH & ChemPubSoc Europe)
NEWS RELEASED by Nikkan Kogyo Shinbun
NEWS RELEASED by The Chemical Daily (Kagaku Kogyo Nippou)
FEATURED in #FeaturedStructureFriday
by Cambridge Crystallographic Data Centre (CCDC)
- "Bimodal Coordination of Fused Arenes to a Pd3 Cluster Site"
Sugawa, T.; Yamamoto, K.; Murahashi, T.
Chem. Commun. 2018, 54, 5875-5878
.
- "Contiguous Multiple π-Coordination of π-Conjugated Polyenes:
Bonding Nature and Charge Delocalization Behaviour of Polyene-(Palladium
Chain) Sandwich Clusters"
Yamane, M.; Yamashita, M.; Yamamoto, K.; Murahashi, T.
Phys. Chem. Chem. Phys. 2018, 20, 4287-4296
. (Special Issue on Complex Molecular Systems: Supramolecules, Biomolecules
and Interfaces)
- "Bridging Coordination of Vinylarenes to Pd3- or Pd4 Cluster Sites"
Ishikawa, Y.; Kimura, S.; Yamamoto, K.; Murahashi, T.
Chem. Eur. J. 2017, 23, 14149-14152
.
- "Recent Advances in the Chemistry of Palladium Complexes: New Structures
and Reactivities Derived from Intermediate Valency" (in Japanese)
Murahashi, T.
Kagaku (Kyoto, Japan), 2017, 72, 64-65 (Highlight).
- "Substrate Binding by a Parallel Metal Sheet Sandwich Complex: A Unique
Role of an Additional Metal Atom"
Ishikawa, Y.; Yamamoto, K.; Murahashi, T.
Angew. Chem. Int. Ed. 2017, 56, 1346-1350
; Angew. Chem. 2017, 129, 1366-1370.
- "A Mechanistic Insight into Metal-Cluster π-Envelopment: A Dual
Binding Mode Involving Bent and Planar Ligand-Conformers"
Masai, K.; Shirato, K.; Yamamoto, K.; Kurashige, Y.; Murahashi, T.
Chem. Commun. 2016, 52, 6427-6430
.
- "σ-π Continuum in Indole-Pd(II) Complexes"
Yamamoto, K.; Kimura, S.; Murahashi, T.
Angew. Chem. Int. Ed. 2016, 55, 5322-5326
; Angew. Chem. 2016, 128, 5408-5412.
- "Dinuclear Palladium(I) Sandwich Complexes of Furan and Toluene"
Yamamoto, K.; Ishikawa, Y.; Kimura, S.; Murahashi, T.
C. R. Chim. 2015, 18, 785-789
. (Special Issue on the South Europe-Japan Forum on Inorganic Chemistry,
Strasbourg 2014)
- "Multinuclear Metal Binding Ability of a Carotene"
Horiuchi, S.; Tachibana, Y.; Yamashita, M.; Yamamoto, K.; Masai, K.; Takase,
K.; Matsutani, T.; Kawamata, S.; Kurashige, Y.; Yanai, T.; Murahashi, T.
Nature Commun. 2015, 6, 6742
. (Open Access)
NEWS RELEASED by The Science News (Kagaku Shinbun)
- "Modulation of Benzene or Naphthalene Binding to Palladium Cluster
Sites by the Backside-Ligand Effect"
Ishikawa, Y.; Kimura, S.; Takase, K.; Yamamoto, K.; Kurashige, Y.; Yanai T.; Murahashi, T.
Angew. Chem. Int. Ed. 2015, 54, 2482-2486.
; Angew. Chem. 2015, 127, 2512-2516.
NEWS RELEASED by The Chemical Daily (Kagaku Kogyo Nippou)
- "Anti dinuclear adducts of cycloheptatriene and cycloheptatrienyl ligands: Anti-[Pd2(μ-C7H8)(PPh3)4][BF4]2 and anti-[M2(μ-C7H7)(PPh3)4][BF4] (M = Pd, Pt)"
Yamamoto, K.; Teramoto, M.; Usui, K.; Murahashi, T.
J. Organomet. Chem. 2015, 784, 97-102.
(Special Issue on the 11th JOM Symposium, Singapore 2014)
- "Bis-cyclooctatetraene Tripalladium Sandwich Complexes"
Murahashi, T.; Kimura, S.; Takase, K.; Uemura, T.; Ogoshi, S.; Yamamoto,
K.
Chem. Commun. 2014, 50, 820-822.
- "Trinuclear Palladium Addition to Unsaturated Carbocycles"
Murahashi, T.; Takase, K.; Usui, K.; Kimura, S.; Fujimoto, M.; Uemura,
T.; Ogoshi, S.; Yamamoto, K.
Dalton Trans. 2013, 42, 10626-10632.
- "Bridging π-Coordination of Pyrrole and Indole over a PdI-PdI Bond"
Murahashi, T.; Kimura, S.; Takase, K.; Ogoshi, S.; Yamamoto, K.
Chem. Commun. 2013, 49, 4310-4312.
(Special Issue on "Emerging Investigators 2013")
- "Selective Construction of Pd2Pt and PdPt2 Triangles in a Sandwich Framework: Carbocyclic Ligands as Scaffolds for
a Mixed-Metal System"
Murahashi, T.; Usui, K.; Tachibana, Y.; Kimura, S.; Ogoshi, S.
Chem. Eur. J. 2012, 18, 8886-8890.
- "Redox-induced Reversible Metal Assembly through Translocation and Reversible Ligand Coupling in Tetranuclear Metal Sandwich Frameworks"
Murahashi, T.; Shirato, K.; Fukushima, A.; Takase, K.; Suenobu, T.; Fukuzumi, S. Ogoshi, S.; Kurosawa, H.
Nature Chem.2012, 4, 52-58.
- "Oxidative Dinuclear Addition of a PdI-PdI Moiety to Arenes: Generation of μ-η3:η3-Arene-PdII2 Species"
Murahashi, T.; Takase, K.; Oka, M.; Ogoshi, S.
J. Am. Chem. Soc. 2011, 133, 14908-14911.
- "Dimensionally Extended Organometallic Sandwich Compounds" (in Japanese)
Murahashi, T.
Organomet. News, 2011, 37-44 (accounts).
- "Formation and Coordination Modes of the C4E4 Moiety (E = COOMe) Bound to Two Palladium(II) Moieties"
Murahashi, T.; Okuno, T.; Usui, K.; Takase, K.; Ogoshi, S.; Kurosawa, H.
Dalton Trans. 2011, 40, 2383-2387.
(Special Issue on "New Talent Asia")
- "Metallocenoids of Platinum: Syntheses and Structures of Triangular Triplatinum Sandwich Complexes of Cycloheptatrienyl"
Murahashi, T.; Usui, K.; Inoue, R.; Ogoshi, S.; Kurosawa, H.
Chem. Sci. 2011, 2, 117-122.
- "Chemistry of Supersized Sandwich Compounds" (in Japanese)
Murahashi, T.
Kagaku & Kogyo, 2009, 62, 1178-1181 (An account for public).
FEATURED in the Cover.
- "Synthesis and Reversible Reductive Coupling of Cationic, Dinitrogen-Derived Diazoalkane Complexes"
Curley, J. J.; Murahashi, T.; Cummins, C. C.
Inorg. Chem. 2009, 48, 7181-7193
.
- "Square Tetrapalladium Sheet Sandwich Complexes: Cyclononatetraenyl as a Versatile Face-Capping Ligand"
Murahashi, T.; Inoue, R.; Usui, K.; Ogoshi, S.
J. Am. Chem. Soc. 2009, 131, 9888-9889
.
- "Synthesis of Multinuclear Sandwich Compounds - Arrangement of Metal Atoms in the Space between Conjugated Unsaturated Hydrocarbons" (in Japanese)
Murahashi, T.
Kagaku (Kyoto, Japan), 2008, 63, 46-51 (An account for public).
- "Structures of Two Haptotropic Isomers Generated by the Sliding of 1,3,5-Triene Ligands on a Pd-Pd-Pd Chain
Murahashi, T.; Mino, Y.; Chiyoda, K.; Ogoshi, S.; Kurosawa, H.
Chem. Commun. 2008, 4061-4063
.
- "Reductive Coupling of Metal Triangles in Sandwich Complexes"
Murahashi, T.; Hashimoto, Y.; Chiyoda, K.; Fujimoto, M.; Uemura, T.; Inoue, R.; Ogoshi, S.; Kurosawa, H.
J. Am. Chem. Soc. 2008, 130, 8586-8587
.
- "Organometallic Multinuclear Sandwich Complexes" (in Japanese)
Murahashi, T.
Bull. Jpn. Soc. Coord. Chem. 2008, 51, 31-40. (An award Accout on JSCC Award for Young Chemists)
- "Synthesis and Structure of Dipalladium Complexes Containing Cyclooctatetraene and Bicyclooctatrienyl Ligands"
Murahashi, T.; Kato, N.; Ogoshi, S.; Kurosawa, H.
J. Organomet. Chem. 2008, 693, 894-898
(Special Issue on the 7th JOM Symposium at Boston).
- "A Stable Zerovalent Palladium Chain Enveloped by a π-Electron
Sheath of Conjugated Polyene Ligands"
Tatsumi, Y.; Murahashi, T.; Okada, M.; Ogoshi, S.; Kurosawa, H.
Chem. Commun. 2008, 477-479
.
- "Discrete Triangular Tripalladium Sandwich Complexes of Arenes"
Murahashi, T.; Fujimoto, M.; Kawabata, Y.; Inoue, R.; Ogoshi, S.; Kurosawa, H.
Angew. Chem. Int. Ed. 2007, 46, 5440-5443
; Angew. Chem. 2007, 119, 5536-5539.
HIGHLIGHTED in Annu. Rep. Prog. Chem. Sec. A. 2008.
- "Rearrangement of a Pd4 Skeleton from a 1D Chain to a 2D Sheet on the Face of Perylene or Fluoranthene Ligand Caused by Exchange of the Binder Molecule"
Murahashi, T.; Kato, N.; Uemura, T.; Kurosawa H.
Angew. Chem. Int. Ed. 2007, 46, 3509-3512
; Angew. Chem. 2007, 119, 3579-3582.
HIGHLIGHTED in Nachtichten aus der Chemie, 2008, 249, Trendberichte 2007.
- "Sandwich Complexes Containing Bent Palladium Chains"
Tatsumi, Y.; Shirato, K.; Murahashi, T.; Ogoshi, S.; Kurosawa, H.
Angew. Chem. Int. Ed. 2006, 45, 5799-5803
; Angew. Chem. 2006, 118, 5931-5935.
- "Discrete Sandwich Compounds of Monolayer Palladium Sheets"
Murahashi, T.; Fujimoto, M.; Oka, M.; Hashimoto, Y.; Uemura, T.; Tatsumi, Y.; Nakao, Y.; Ikeda, A.; Sakaki, S.; Kurosawa, H.
Science, 2006, 313, 1104-1107
.
HIGHLIGHTED in THIS WEEK in SCIENCE 
HIGHLIGHTED in Chem & Eng. News, 2006, Aug. 28, 8. 
SELECTED as the TOP 10 PAPERS (2006-2007) published by the researchers of OSAKA
UNIVERSITY.
FEATURED in Kagaku, 2008, 63, 46 (in Japanese).
- "Dinuclear Addition of the Pd-Pd Moieties to 1,3-Dienes"
Murahashi, T.; Nagai, T.; Nakashima, H.; Tomiyasu, T.; Kurosawa, H.
Chem. Lett. 2006, 754-755
.
- "Stereoretentive Elimination and Trans-Olefination of the Dicationic
Dipalladium Moiety [Pd2Ln]2+ Bound on 1,3,5-Trienes
Murahashi, T.; Nakashima, H.; Nagai, T.; Mino, Y.; Okuno, T.; Jalil, M. A.; Kurosawa, H.
J. Am. Chem. Soc. 2006, 128, 4377-4388
.
- "A Ligand Composed of Dinitrogen and Diphenylmethylphosphane in a Cationic Molybdenum Complex"
Murahashi, T.; Clough, C. R.; Figueroa, J. C.; Cummins, C. C.
Angew. Chem. Int. Ed. 2005, 44, 2560-2563
; Angew. Chem. 2005, 117, 2616-2619.
SELECTED as a Very Important Paper (VIP) of this journal.
HIGHLIGHTED in Nachrichten aus der Chemie, 2005, 724.
- "Stepwise Growth of Palladium Chains in 1,4-Diphenyl-1,3-Butadiene Sandwich Complexes"
Tatsumi, Y.; Nagai, T.; Nakashima, H.; Murahashi, T.; Kurosawa, H.
Chem. Commun. 2004, 1430-1431
.
- "Perylene Tetrapalladium Sandwich Complexes"
Murahashi, T.; Uemura, T.; Kurosawa, H.
J. Am. Chem. Soc. 2003, 125, 8436-8437
.
- "Synthesis and Structure of Organo-polypalladium Complexes"
Murahashi, T.; Kurosawa, H.
J. Synth. Org. Chem. Jpn. 2003, 61, 652-666.
- "New Direction in Organopalladium Chemistry: Structure and Reactivity of Unsaturated Hydrocarbon Ligands Bound to Multipalladium Units"
Murahashi, T.; Ogoshi, S.; Kurosawa, H.
Chemical Record 2003, 3, 101-111
.
- "Photo-Induced Face-Inversion of Conjugated Tetraene Ligands on a Pd-Pd-Pd Moiety"
Murahashi, T.; Higuchi, Y.; Katoh, T.; Kurosawa, H.
J. Am. Chem. Soc. 2002, 124, 14288-14289
.
- "Synthesis and Reactivity of a Palladium(I)-Palladium(I)-Bonded μ-Hydroxo
Complex Supported by a Bridging Butadiene Ligand"
Jalil, M. A.; Nagai, T.; Murahashi, T.; Kurosawa, H.
Organometallics, 2002, 21, 3317-3322
.
- "Organopalladium Complexes Containing Palladium-Palladium Bonds" (Review)
Murahashi, T.; Kurosawa, H.
Coord. Chem. Rev. 2002, 231, 207-228
.
- "Generation of Oligoene Species Capped by Pd(II) Moieties from Dinuclear Palladium(I) Complex and Alkyne"
Murahashi, T.; Okuno, T.; Nagai, T.; Kurosawa, H.
Organometallics, 2002, 21, 3679-3682
.
- "Reversible Interconversion between Dinuclear Sandwich and Half-Sandwich
Complexes: Unique Dynamic Behavior of a Pd-Pd Moiety Surrounded by a sp2-Carbon Framework"
Murahashi, T.; Nagai, T.; Mino, Y.; Mochizuki, E.; Kai, Y.; Kurosawa, H.
J. Am. Chem. Soc. 2001, 123, 6927-6928
.
- "Novel Coordination Behavior of Unsaturated Hydrocarbon Ligands on Pd-Pd Bonds"
Kurosawa, H.; Murahashi, T.
Pure & Appl. Chem. 2001, 73, 295-298
.
- "Synthesis and Destannylation of η3-1-Stannylallylpalladium(II) Complexes"
Nishida, T.; Watanabe, S.; Yoshida, T.; Ogoshi, S.; Murahashi, T.; Kurosawa, H.
J. Organomet. Chem. 2001, 625, 54-57
.
- "Synthesis and Ligand Substitution Reaction of Homoleptic Acetonitrile Dipalladium(I) Complex"
Murahashi, T.; Nagai, T.; Okuno, T.; Matsutani, T. Kurosawa, H.
Chem. Commun. 2000, 1689-1690
.
- "Coupling of Alkynes on a Pd-Pd Bond to Generate an Electrophilic
μ-Butenediylidene Moiety"
Murahashi, T.; Otani, T.; Okuno, T.; Kurosawa, H.
Angew. Chem. Int. Ed. Engl. 2000, 39, 537-540
; Angew. Chem. 2000, 112, 547-550.
- "Organometallic Sandwich Chains Made of Conjugated Polyenes and Metal-Metal Chains"
Murahashi, T.; Mochizuki, E.; Kai, Y.; Kurosawa, H.
J. Am. Chem. Soc. 1999, 121, 10660-10661
.
HIGHLIGHTED in Angew. Chem. Int. Ed. 2002, 41, 4453.
HIGHLIGHTED in Chem. Ind.1999
- "Synthesis and Structure of 1,3-dienolate (CH2C(O)CH=CH2) Complex of Dipalladium(I) Moiety: Contribution of π-olefin Coordination
of Enolate to Transition Metal"
Murahashi, T.; Kurosawa, H.
J. Organomet. Chem. 1999, 574, 142-147
. (Special Issue Dedicated to the Memory of the Late Professor R. Okawara
(Osaka Univ. Emeritus) )
- "Remarkably Wide Range of Bond Distance Adjustment of d9-d9 Pd-Pd Interactions to change in Coordination Environment"
Murahashi, T.; Otani, T.; Mochizuki, E.; Kai, Y.; Kurosawa, H.; Sakaki, S.
J. Am. Chem. Soc. 1998, 120, 4536-4537
.
- "Synthesis of a Tripalladium Cluster Containing an η1:η2:η2-Bridging Butadienyl Ligand Stabilized by a Zwitterionic Structure"
Murahashi, T.; Kurosawa, H.; Kanehisa, N.; Kai, Y.
J. Organomet. Chem. 1997, 530, 187-189
.
- "Rational Synthesis of Anionic, Neutral and Cationic Palladium(I) Dinuclear Complexes Containing Bridging Conjugated Dienes"
Murahashi, T.; Kanehisa, N.; Kai, Y.; Otani, T.; Kurosawa, H.
Chem. Commun. 1996, 825-826
.
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